Biodiesel Fuel Production, Bio-diesel Kit ... - Castor Oil The methyl ester content under these optimum conditions was 94.5% w/w of oil, and all of the measured properties Besides that, biodiesel produced from castor oil is low cost compared to production of biodiesel from other oils regarding to its solvability in alcohol transesterification could occur without usage of many excess heating equipment Biodiesel production through chemical technology, that is, transesterification, has been developed and widely used. Abstract Biodiesel is evolving to be one of the most employed biofuels for partial replacement of petroleum based diesel fuel, especially in recent years. Mechanical and chemical oil extraction procedures were evaluated. Rubens Maciel. This work presents the biodiesel production from castor oil with bioethanol from sugar cane (also called here ethanol) in presence of sodium ethoxide and sodium hydroxide as catalysts. • The Indian variety of castor has 48% oil content of which 42% can be extracted, while the cake retains the rest. In this work, biodiesel production from castor oil has been synthesized by homogenous alkaline transesterification. This work presents the biodiesel production from castor oil with bioethanol from sugar cane (also called here ethanol) in presence of sodium ethoxide and sodium hydroxide as catalysts. Biodiesel is usually prepared in the presence of homogeneous base or acid catalysts. Nívea De Lima da Silva. he biodiesel yield he biodiesel yield increases with the . cases make castor oil and ricinoleic acid becoming one of valuable chemical feedstocks (Chakrabarti and Ahmad, 2008). Biodiesel is evolving to be one of the most employed biofuels for partial replacement of petroleum based diesel fuel, especially in recent years. castor oil respectively while biodiesel yield from refined and unrefined castor oil was 43.5 and 41.7% respectively. • Gujarat is the largest producer of Castor seed in India. The base catalyzed transesterification under different reactant proportion such as the molar ratio of alcohol to oil and mass ratio of catalyst to oil was studied for optimum production of castor biodiesel. 2.2. R. Filho. The acid-based catalyzed transesterification system was used to produce castor biodiesel and the highest yield of 82.5% was obtained under the optimized condition. The studied variables were reaction temperature, catalyst concentration, and ethanol:castor oil molar ratio. Keywords:Surfactant, Fatty Methyl Ester, Castor Oil Fatty Acid Methyl Ester,Free fatyacid,Castor Oil 1. Catalyst reusability test shows that the synthesized calcium oxide from mud clam shell is reusable up to 5 times. Oil percentage was in R. communis 48%. Response surface methodology was used to optimize the transesterification reaction in traditional conditions. The production of biodiesel was optimized by the use of a two-step process. These and other reasons have led to medium- and large-scale biodiesel production trials in several countries, using non-edible oils such as castor oil, tung, cotton, jojoba and jatropha. Box 6066, 13081-970, Campinas, SP, Brazil Received May 4, 2009. About chemical and physical characteristics, castor oil composition is 80-90 % ricinoleic acid, 3-6 % linoleic acid, 2-4 % oleic acid and 1-5 % saturated fatty acids [1]. In this study, the optimum biodiesel conversion from crude castor oil to castor biodiesel (CB) through transesterification method was investigated. Download Free PDF. Optimization of Biodiesel Production from Castor Oil Using Response Surface Methodology. For physicochemical characterization oil qualities were measured such as acid The flash point values of castor methyl esters are lower than that of castor oil. Characterization of oil Oil percentage was from R. communis 48. With Biodiesel Manufacturing Plant | Biodiesel Plant Suppliers biodiesel production lies in the fact that no foodstuffs are spent to produce fuel [4]. The pretreated castor oil was ready to be used for biodiesel production. Pages 3 This preview shows page 1 - 2 . Energy Security 3. A factorial design was Understanding the kinetics of this reaction is important to achieve higher production rates. Since the energy provided by biodiesel is slightly (about 10%) lower than that of petro-fuels, the world would require about 5.5 billion T of bio-diesel to completely replace petro-diesel, at the current levels of consumption. 73 ©2020 Gomes et al. From the titration method, the acid value. 3.1. Biodiesel can be produced by transesterification with methanol or ethanol using an acid or alkaline catalyst; however, the process of biodiesel/glycerine separation is even more difficult. The refined oil contained 0.8% free fatty acid (FFA) and 76.258mg KOH/g saponification value which showed that oil was very suitable for biodiesel production. Jeong and Park optimized the biodiesel production from castor oil using response surface methodology. Meneghetti et al. Islam . The most widely used feedstocks for biodiesel production are vegetable oils. Waste MFL seed shells, carbonized and steam activated for surface modification to enhance adsorptive properties were then doped with H 2 SO 4 to develop a heterogeneous catalyst capable of facilitating esterification of the oil to form an ester rich product. Castor oil contains 80-90% of hydroxyl fatty acid, ricinoleic acid and about10% non-hydroxylated fatty acids, mainly oleic and linoleic acids.Such especial composition causes a disadvantage for its use for biodiesel production, since its viscosity is about 7 times higher than the one of other vegetable oils .To avoid this disadvantage, castor oil biodiesel when blends with petrodiesel it has . synthesis processes, biodiesel productionand many referencescan be found in the background literature [33, 47-49]. J Anal Pharm Res. Nivea Silva. diesel production as it is time saving, and we can opti-mize biodiesel production on the pilot scale with the experimental data optimized by using ANN. Additionally, biodiesel from castor oil has different advantages over conventional diesel. Chapter 2 Introduction to Biodiesel Production biodiesel production lies in the fact that no foodstuffs are spent to produce fuel [4]. Biodiesel can be synthesized by transesterification process using acid or base catalyst. With increase in the demand of petroleum products the prices of petrol & diesel are increasing worldwide. The crude castor oil was then degummed with aqueous sulfuric acid to remove gum content of the oil as described by Akpan et al. Figure 7 Yield. In order to address this issue, we conducted a study to assess the potential of castor oil, an inedible vegetable oil, as a biodiesel feedstock, and we . Biodiesel is produced through a refinery process called transesterification reaction of vegetable oils and animal fat. A highest biodiesel yield of 96.7% was obtained at optimal parameters such as 1 : 14 oil-to-methanol molar ratio, 3% w/w catalyst concentration, 60°C reaction temperature, and 2-hour reaction time. of vegetable oil such as castor oil, jatropha oil, and soybean oil. are being considered worldwide. However, the majority of the biodiesel production is from energy crops, such as palm oil and soybean, while waste animal fat and vegetable oils have been proposed as suitable feedstock for biodiesel production only in recent years. The kinetics of transesterification of castor oil using Novozym 435 was investigated in this study. he experimental results were illustrated in Figure 5 shows the biodiesel yield from transesteriication of castor indicating that the molar ratio of methanol to oil has a oil at diferent reaction temperature from 50∘ C to 70∘ C. signiicant impact on the biodiesel yield. The use of biodiesel and the requirement of improving its production in a more efficient and sustainable way are becoming more and more important. Animal fats are he biodiesel yield he biodiesel yield increases with the . Recently, the use of castor oil has attracted attention for producing and optimizing biodiesel production, due to high content of ricinoleic fatty acid and the possibility to esterify with only methanol, which assures low production costs. A process for obtaining turbo biofuel from castor oil wherein the oil, methanol and sodium hydroxide previously diluted in said methanol, are reacted by transesterification at a temperature less than 40°C and for a maximum time of 60 minutes; it is decanted; formed glycerin, is removed; it is neutralized with acid; it is washed with water in at least two steps; the aqueous phase from the last . If the limit of FFA is exceeded, then soap formation occurs which inhibits the suppres-sion of ester [20]. Castor was seeded, plants grew and seeds were manually harvested after 2 years. Ricinoleic acid (84.9%) was prevalent in the oil with lignoceric (0.03%) as the smallest. of FF A in crude castor oil was determined. are being considered worldwide. of RC biodiesel meet most of the specifications of EN590. The castor oil was then pretreated with acid esterification to reduce the free fatty acid contents of the oil to less than 0.5% . cases make castor oil and ricinoleic acid becoming one of valuable chemical feedstocks (Chakrabarti and Ahmad, 2008). production process of biodiesel from palm oil [3]. Biodiesel Manufacturing Plant | Biodiesel Plant Suppliers biodiesel production lies in the fact that no foodstuffs are spent to produce fuel [4]. If 10% of total production of castor seed oil is transesterfied into biodiesel, then about 79,782 tones of CO2 emission can be saved on annual basis. 2020;9(3):73‒79. Other groups have applied RSM in an effort to optimize process factors for biodiesel production, using rapeseed oil, soybean oil, cottonseed oil, castor oil, and lard [12, 17, 19-21]. The experimental design was used in the optimization process because this methodology permitted a . Download Free PDF. castor oil.pdf - International Journal of Current. he experimental results were illustrated in Figure 5 shows the biodiesel yield from transesteriication of castor indicating that the molar ratio of methanol to oil has a oil at diferent reaction temperature from 50∘ C to 70∘ C. signiicant impact on the biodiesel yield. These and other reasons have led to medium- and large-scale biodiesel production trials in several countries, using non-edible oils such as castor oil, tung, cotton, jojoba and jatropha. Castor oil is an excellent raw material in terms of price and quality, but especially this non-edible vegetable oil does not have any issues or compromise food security. In such a study, maximum yields of esters were obtained after 1h of reaction time with methanol or 5 h with ethanol. With increase in the demand of petroleum products the prices of petrol & diesel are increasing worldwide. Introduction fluctuations have generated the desirability to develop 1.1 Background renewable fuels to Abstract— Current study reveals the production of biodiesel from non-edible oil such as castor oil (Ricinus Communis L.). The waste eggshell powder was calcined in air at 90° C for 4 h to convert calcium species in the eggshells into active CaO catalysts. Castor (Ricinus communis) beans were subjected for the extraction of oil which contained 48% yield. The most widely used feedstocks for biodiesel production are vegetable oils. Biodiesel is considered an alternative replacement for petroleum diesel, and enzymatic reaction is one method for biodiesel production. Both the edible and non-edible vegetable oils can be used as the raw materials for the biodiesel. The results obtained show a 95.20% yield under optimal conditions (1:8 oil:methanol, 11% of catalyst, 60 min, Biodiesel production through chemical technology, that is, transesterification, has been developed and widely used. The conformity of refined castor oil biodiesel with EN 14214, ASTM and India biodiesel standards makes it viable economically in Nigeria. Biodiesel is a potential substitute of energy because it is ob-tained from renewable energy sources. Castor belongs to the Euphorbiaceae family. Although palm oil seems to be a promising source of biodiesel in Colombia because of the productive capacity already in place, it was decided to explore the production of the biofuel from castor oil. Castor was seeded, plants grew and seeds were manually harvested after 2 years. Biodiesel production is a very modern and technological area for researchers due to the relevance that it is winning every day because of the increase in the petroleum price and the environmental advantages (Aburas and Demirbas, 2015b; Marchetti et al., 2007).Biodiesel can be derived from a variety of sources including vegetable oils, animal fats, and waste cooking oil. As the production of castor seeds present high oil levels thereby ensuring a respectable productivity per hectare is planted.12,13 Despite the advantages mentioned the biodiesel from castor oil faces challenges. Industrially, the most common method for biodiesel production is a basic . Cesar Benedito Batistella. The best . Oil was extracted from seed by mechanical press method. Applied Biochemistry and Biotechnology, 2009. than 4%. • India supplies over 70% of the total production of castor oil in the world. However, the majority of the biodiesel production is from energy crops, such as palm oil and soybean, while waste animal fat and vegetable oils have been proposed as suitable feedstock for biodiesel production only in recent years. transesterification for biodiesel production. This work presents the biodiesel production from castor oil with bioethanol from sugar cane (also called here ethanol) in presence of sodium ethoxide and sodium hydroxide as catalysts. The reported study discusses biodiesel production from castor oil using methanol. Both the edible and non-edible vegetable oils can be used as the raw materials for the biodiesel. . A preliminary assessment of castor plant adaptability at Northern Portugal was performed, together with the evaluation of the extracted raw oil, without any refinement, for biodiesel production. As the free fatty acid content in castor oil is more than 1%, an acid catalyst namely, H 2 SO 4 has been used for esterification. The CO. 2. released during combustion of biodiesel can be re-cycled through next crop production, therefore, no addi-tional burden on environment [7]. A solid CaO-based catalyst of waste eggshell was developed for biodiesel production from used cooking oil. Energy Fuels 2009, 23, 5636-5642 : DOI:10.1021/ef900403j Published on Web 11/02/2009 Biodiesel Production from Castor Oil: Optimization of Alkaline Ethanolysis Nı´ vea de Lima da Silva,* C esar Benedito Batistella, Rubens Maciel Filho, and Maria Regina Wolf Maciel School of Chemical Engineering, State University of Campinas P.O. bran oil, mahua oil, and castor oil (ricinus communis) might be studied and explored as a feedstock for biodiesel production [8-10]. Research Article Biodiesel Production from Castor Oil by Using Calcium Oxide Derived from Mud Clam Shell S.Ismail, 1 A.S.Ahmed, 2 ReddyAnr, 2 andS.Hamdan 2 Department of Chemical Engineering, Faculty of Engineering, Universiti Malaysia Sarawak (UNIMAS), modification or can be used as affecting the yield of biodiesel production from castor blending agent for diesel [3]. In this study, castor oil from non-edible oil resources is selected as a feedstock for biodiesel production due to its higher oil content. to be between 20% to 23%, which is higher. These and other reasons have led to medium- and large-scale biodiesel production trials in several countries, using non-edible oils such as castor oil, tung, cotton, jojoba and jatropha. Hence alternative sources of energy for running our generators, automobiles etc. School KL University; Course Title MECHANICAL 16ME2210; Uploaded By DoctorMonkey6448. Chapter 2 Introduction to Biodiesel Production biodiesel production lies in the fact that no foodstuffs are spent to produce fuel [4]. The characterization of CaO catalyst was done by XRD and BET analysis. Ni-doped ZnO nanocatalyst for biodiesel production using castor oil as a feedstock. The studied variables were reaction temperature, catalyst concentration, and ethanol:castor oil molar ratio. In fact, castor oil has one of the highest cetane numbers amongst vegetable oils, and all the other biodiesel contenders have cetane numbers slightly lower than that for castor oil (The cetane number of petro diesel is about 45, while for most biodiesel, the cetane number falls in the range 45-65) (See Biodiesels from Vegetable Oils - PDF) These and other reasons have led to medium- and large-scale biodiesel production trials in several countries, using non-edible oils such as castor oil, tung, cotton, jojoba and jatropha. This research work concerns with the transesterification of castor oil with methanol to form biodiesel. Since the source plant is commonly found in a wild state in many parts of the a renewable energy source. Abstract. Animal fats are Recently, the use of castor oil has attracted attention for producing and optimizing biodiesel production, due to high content of ricinoleic fatty acid and the possibility to . Assessment of Low Temperature Refining Process of Castor Seed Oil for Biodiesel Production Figure 1. The total world production of vegetable oils was only about 0.06 billion T in 2005. Castor seeds. The predicted optimum conditions for castor oil biodiesel production were a reaction temperature of 59.89 0c, methanol to oil ratio of 8.10:1 and a catalyst of 1.22 wt% of oil. Ricinoleic The objective of study this was to study the conventional reactive extraction and the reactive extraction via ultrasound waves for the biodiesel production from castor oil seeds. 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